When a fire is deliberately set, the person often uses an accelerant — a substance, usually an ignitable liquid such as petrol, to start the fire or make it spread faster and hotter. Detecting accelerants is a key part of distinguishing arson from an accidental blaze.

Signs at the scene

Accelerant use can leave tell-tale traces:

  • irregular "pour" patterns on floors, where liquid ran and burned,
  • unusually rapid or intense fire spread inconsistent with the available fuel,
  • multiple, separate points of origin.

None of these is proof on its own — investigators weigh them together and against innocent explanations.

How it's detected

Suspected accelerant is confirmed by a combination of tools:

  • electronic vapour detectors ("sniffers") at the scene,
  • trained accelerant-detection dogs, which can pinpoint tiny traces,
  • and, decisively, laboratory gas chromatography–mass spectrometry (GC-MS) on debris samples, which identifies the specific ignitable liquid.

Interpreting presence and absence

Two cautions matter. Presence of an ignitable liquid isn't automatic proof of arson — many household products and plastics contain or produce hydrocarbons, so context is essential. And absence doesn't rule arson out — accelerants burn away, and many deliberate fires use none at all. As with the rest of fire investigation, the conclusion comes from the whole picture, tested against the science.